Product ID:LEADED PETROL
MSDS Date:06/19/1990
FSC:9130
NIIN:00N030685
MSDS Number: BPGRW

CALTEX INC

540 PADRE FAURA ST
ERMITA, MANILA, PHILIPPINES

Emergency Phone: 5231-35-01

Info Phone: 5231-35-01

Cage: 0BET2

CALTEX INC

ERMITA, MANILA, PHILIPPINES

Telephone: 521-35-01

Cage: 0BET2

GASOLINE (CONSISTS OF MAINLY STRAIGHT CHAIN AND BRANCHED

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM;500 PPM STEL

ACGIH TLV: 300 PPM;500 PPM STEL

BENZENE

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0.5-4.0%

ACGIH TLV: 0.1 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

CERTAIN EPIDEMIOLOGY STUDIES HAVE INDICATED THAT

RTECS: 9999999ZZ

FORMING ORGANS INCL LEUKEMIA. WHILE BENZENE CONTENT

RTECS: 9999999ZZ

EXPOS TO SKIN & RESP SYS TO WELL W/IN CURRENT EXPOS

RTECS: 9999999ZZ

TO REMOVE. EMPTY DRUMS SHOULD BE COMPLETELY

RTECS: 9999999ZZ

RECONDITIONER. ALL OTHER CONTR SHOULD BE DISPOSED OF

RTECS: 9999999ZZ

PREFILTER. IN ABSENCE OF LOC APPRVD AUTH, FOLLOW

RTECS: 9999999ZZ

NIOSH/MSHA APPRVD SUPPLIED AIR RESP PROT FOR CLEANING

RTECS: 9999999ZZ

OTHER CONFINED SPACES. IN ABSENCE OF LOCAL APPROVAL

RTECS: 9999999ZZ

CONTROLS MAY BE NEEDED. LOCAL EXHAUST VENT &/OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES:MAY CAUSE MOD IRRIT. INGEST:
EXPECTED TO HAVE MOD ACUTE TOX BY INGEST. INHAL: MAY CAUSE DIZZ,
IRRIT OF EYES, NOSE & THROAT, VOMIT, & CNS EFTS UPON INHAL.
CONVULS, SEIZURES & SUDDEN LOSS OF CONSCI OUSNESS, COMA & DEATH ARE
POSS FROM EXTREME EXPOS. SKIN:MOD IRRITATING TO SKIN & MAY CAUSE
RED, EDEMA, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: OSHA REGULATED, GROUP
1(IARC);KNOWN CARCINOGEN (NTP):GASOLINE GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:/DRYING. MAY PRDCE SYSTEMIC TOX BY
SKIN ABSORP. LIM CHRONIC INHAL TOX STUDIES SHOWED KIDNEY DISEASE &
KIDNEY CANCER WHERE ANIMALS WERE EXPOS TO WHOLLY VAPORIZED PETROL.
ADDNL STUDIES WHICH EV ALUATED EXPOS LIM TO VOLAT FRACTION OF
PETROL DID NOT PRDCE KIDNEY DAM/KIDNEY CANCER. EPIDEMIOLOGY STUDIES
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH IMMED WITH FRESH WATER FOR AT LEAST 15 MIN WHILE
HOLDING LIDS OPEN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER.
INGEST: DO NOT INDUCE VOMIT. ASPIR OF FLUID CAN CAUSE SERIOUS LUNG
INJURY SUC H AS CHEMICAL PNEUMONITIS. CALL MD IMMED. INHAL: MOVE TO
FRESH AIR. IF BREATHING HAS STOPPED, APPLY ARTF RESP. CALL MD.

Flash Point:-40F,-40C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:ACCD TO U.S. NFPA GUIDE, USE DRY CHEM, FOAM/CO2.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. H2O
MAY BE INEFTIVE ON FLAMES, BUT H2O MAY BE USED TO KEEP FIRE-EXPOS
CONTR COOL. IF LEAK/SPILL (SUPP DATA)
Unusual Fire/Explosion Hazard:FLOWING PETROL CAN BE IGNITED BY SELF-
GENERATING STATIC ELEC; USE ADEQ GROUND.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES INCL INTERNAL
COMBUSTION ENGINES, DE-ENERGIZE ELEC EQUIP & SYS. VENT AREA. AVOID
BRTHG VAP. CNTN SPILL IF POSS. REMOVE W/INERT ABSORB. USE
NIOSH/MSHA APPROVED RESP & PRO T CLTHG AS DISCUSSED IN THIS MSDS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/FLAME.
TRANSPORT, HNDLE & STORE I/A/W LOC REGS REGARDING FLAMM LIQ. EMPTY
CONTR RETAIN RESIDUE(LIQ/VAP) & CAN BE DANGEROUS.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE SUCH CONTR TO HEAT, FLAME, SPARKS, STATIC ELEC, OR
OTHER SOURCES OF IGNIT: THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO
NOT ATTEMPT TO CLEAN SINCE RESIDUE IS DFCLT (ING 6)

Respiratory Protection:RESP PROT IS NOT NORMALLY REQD. HOWEVER, IF
OPERATING CNDTNS CREATE AIRBORNE CONC WHICH EXCEED RECOM EXPOS STD,
USE OF AN NIOSH/MSHA APPRVD RESP IS RECOM. WEAR NIOSH/MSHA APPRVD
PROT SUCH AS AN ORG VA P CARTRIDGE RESP W/PARTICULATE (ING 8)
Ventilation:NO SPECIAL VENT IS USUALLY NEC. HOWEVER, IF OPERATING
CNDTNS CREATE HIGH AIRBORNE CONC OF MATL, ENGINEERING (ING 11)
Protective Gloves:NEOPRENE OR NITRILE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:IMPERVIOUS PROT CLTHG. PROT CLTHG MADE FROM
NEOPRENE, NITRILE, OR N-BUTYL RUBBER IS SUITABLE IN THESE
APPLICATIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: HAS NOT IGNITED, USE H2O TO DISPERSE VAPOR & TO
PROVIDE PROT FOR PERSONS ATTEMPTING TO STOP LEAK. EFTS OF OVEREXP:
IN HUMANS EXPOS TO HYDROCARBONS HAVE NOT INDICATED EXCESS RISK OF
KI DNEY CANCER. PETROL CNTNS BENZENE IN CONC FROM ABOUT 0.5-4.0%.
CHRONIC TOX STUDIES IN LAB ANIMALS & CERTAIN & (ING 3)

HCC:F2
Boiling Pt:B.P. Text:>32F,>0C
Vapor Density:3-4
Spec Gravity:0.7-.77
Solubility in Water:SLIGHT
Appearance and Odor:LIGHT STRAW COLOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT.
Hazardous Decomposition Products:CO AND CO2 MAY BE FORMED ON BURNING IN
LIMITED AIR SUPPLY.

Waste Disposal Methods:IT IS RESPONSIBILITY OF USER OF PROD TO DETERM,
@ TIME OF DISP, WHETHER PROD MEETS CRITERIA FOR HAZ WASTE. PROD
USES, TRANSFORMATIONS, MIX & PROCESSES, MAY RENDER RESULTING
MATERIAL HAZARDOUS. DISPOSE I/A/W FED, ST & LOC REGS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.